Electronic state of iron in hemoglobin, myoglobin, and derivatives, as inferred from x-ray fluorescence spectra
نویسندگان
چکیده
• A submitted manuscript is the author's version of the article upon submission and before peer-review. There can be important differences between the submitted version and the official published version of record. People interested in the research are advised to contact the author for the final version of the publication, or visit the DOI to the publisher's website. • The final author version and the galley proof are versions of the publication after peer review. • The final published version features the final layout of the paper including the volume, issue and page numbers.
منابع مشابه
Low frequency vibrational modes of oxygenated myoglobin, hemoglobins, and modified derivatives.
The low frequency resonance Raman spectra of the dioxygen adducts of myoglobin, hemoglobin, its isolated subunits, mesoheme-substituted hemoglobin, and several deuteriated heme derivatives are reported. The observed oxygen isotopic shifts are used to assign the iron-oxygen stretching (approximately 570 cm-1) and the heretofore unobserved delta (Fe-O-O) bending (approximately 420 cm-1) modes. Al...
متن کاملAn Electron Spin Resonance Study of Some Hemoproteins.
The magnetic characteristics of hemoproteins are a manifestat,ion of electron distribution. They are sensitive to the nature of t.he ligands occupying the fifth and sixth coordination positions of the iron atom, which also determine the function of the hemoprotein. Theorell and his school (1) have systematically studied the magnetic properties of various hemoproteins and their derivatives by ma...
متن کاملIron L-Edge X-ray Absorption Spectroscopy of Myoglobin Complexes and Photolysis Products
We demonstrate the first application of L-edge X-ray absorption spectroscopy (XAS) to the electronic characterization of biological photolysis products. The experimental L-edge XAS spectra of deoxymyoglobin (deoxy Mb), oxymyoglobin (MbO2), carbonmonoxymyoglobin (MbCO), and the low-temperature photoproducts (Mb*CO and Mb*O2) are presented and compared to simulated spectra using a ligand field mu...
متن کاملResonance Raman interrogation of the consequences of heme rotational disorder in myoglobin and its ligated derivatives.
Resonance Raman spectroscopy is employed to characterize heme site structural changes arising from conformational heterogeneity in deoxyMb and ligated derivatives, i.e., the ferrous CO (MbCO) and ferric cyanide (MbCN) complexes. The spectra for the reversed forms of these derivatives have been extracted from the spectra of reconstituted samples. Dramatic changes in the low-frequency spectra are...
متن کاملTiCl2/Nano-γ-Al2O3 as a Novel Lewis Acid Catalyst for Promotion of One-pot Synthesis of 1,4-dihydropyridines
Synthesis of organic compounds using nano-catalysts is more and more attention due to the numerous advantages such as cost-effectiveness, high catalytic activity, ease of product separation, recovery of the catalyst, repeated recycling potential and good stability. In this work, TiCl2/nano-γ-Al2O3, as a novel type of green heterogeneous solid acid was prepared by the immobilization of TiCl2 on ...
متن کامل